Name: Reactions of Coordinated Ligands: Volume 1 (en Inglés)
SKU: 56500861
Price: 71.07 USD
Availability: InStock
Author: Braterman, P. S.

portada Reactions of Coordinated Ligands: Volume 1 (en Inglés)

Reactions of Coordinated Ligands: Volume 1 (en Inglés)

Formato

Libro Físico

Editorial

Springer

Autor

Braterman, P. S.

Idioma

Inglés

N° páginas

1064

Encuadernación

Tapa Blanda

Dimensiones

25.4x17.8x5.3 cm

Peso

1.81 kg.

ISBN13

9781461290001

Categorías

Química inorgánica
Química orgánica
Química física

Reactions of Coordinated Ligands: Volume 1 (en Inglés)

Braterman, P. S. (Autor) · Springer · Tapa Blanda

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Reseña del libro "Reactions of Coordinated Ligands: Volume 1 (en Inglés)"

This book is aimed at graduate students and research workers in aU branches of ohemistry, who wish to gain insight into what continues'to be one of the fastest growing areas of the subject. Aonding to a metal center may stabilize a ligand towards some reagents, activate it towards others, or modify its chemical behavior in more subtle ways. AU these effects have their uses, and aU invite understanding in terms of mechanism. Thus mechanistic insight is linked to control of reaction pathways. The detailed working out of this relationship provides the central theme of the book. The effect of the metal may be electronic or steric, and may involve the energy or the entropy of activation. It may depend on changes induced in the initial state of the ligand, or on those that only arise further along the reaction pathway. It may involve one coordination site or several, and the effects may be more, or less, specific to the metal involved and more, or less, amenable to control through the other Jigands. These remarks apply equaUy strongly to the carbon-bound ligands which occupy the major part of this work, and to those attached by other atoms. Thus the reactions discussed here are relevant in such diverse areas as bulk homogeneous catalysis, stereoselective stoichiometric synthesis, and bioinorganic chemistry.